Preparation of Disyndiotactic Poly(methyl crotonate) by Stereospecific Group Transfer Polymerization
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چکیده
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preparation of polystyrene nanocomposite by in situ atom transfer radical polymerization: study of polymerization kinetics in the presence of clay
styrene nanocomposites were synthesized by in-situ atom transfer radical polymerization at 110oc. the variations of monomer conversion and the linearity of semilogarithmic kinetic plot, some signs of living polymerizationand constant radical concentration in the reaction medium, were revealed by gas chromatography technique (gc). according to the gel permeation chromatography (gpc) results, the...
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Polymers bearing polar functionalities are important materials, since they exhibit beneficial properties with respect to adhesion, paint/printability and surface properties. Commercial synthesis of these materials is mainly based on radical processes, which (so far) only allow poor control over the stereochemistry of the resulting polymers. 2 ] Stereo-controlled polymerisation generally require...
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A moment equations method was performed to study the Reversible chain Transfer Catalyzed Polymerization (RTCP) of styrene in 80°C. To do this, a kinetic scheme containing conventional free radical polymerization reactions and equilibrium reactions of RTCP was assumed. After obtaining mass balance equations, three moment equations were defined for free and dormant radicals and dead chains. M...
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ژورنال
عنوان ژورنال: Polymer Journal
سال: 1999
ISSN: 0032-3896,1349-0540
DOI: 10.1295/polymj.31.177